Thermal Analysis of Polymers, Fundamentals and Applications(1).pdf

THERMAL ANALYSIS OF

POLYMERS

THERMAL ANALYSIS OF

POLYMERS

Fundamentals and Applications

EDITED BY

JOSEPH D. MENCZEL

Alcon Laboratories

Fort Worth TX

R. BRUCE PRIME

San Jose, CA

A JOHN WILEY & SONS, INC., PUBLICATION

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Library of Congress Cataloging-in-Publication Data:

Thermal analysis of polymers: fundamentals and applications / edited by Joseph D. Menczel,

R. Bruce Prime.

p. cm

Includes bibliographical references and index.

ISBN 978-0-471-76917-0 (cloth)

1. Polymers–Analysis. 2. Thermal analysis. I. Menczel, Joseph D. II. Prime, R. Bruce.

QD139.P6.T4452008

547′.7046—dc22

2008024101

Printed in the United States of America

10 9 8 7 6 5 4 3 2 1

CONTENTS

PREFACE

1 INTRODUCTION

Joseph D. Menczel, R. Bruce Prime and Patrick K. Gallagher

2 DIFFERENTIAL SCANNING CALORIMETRY (DSC)

Joseph D. Menczel, Lawrence Judovits, R. Bruce Prime,

Harvey E. Bair, Mike Reading, and Steven Swier

2.1. Introduction / 7

2.2. Elements of Thermodynamics in DSC / 9

2.3. The Basics of Differential Scanning Calorimetry / 18

2.4. Purity Determination of Low-Molecular-Mass Compounds by

DSC / 37

2.5. Calibration of Differential Scanning Calorimeters / 41

2.6. Measurement of Heat Capacity / 52

2.7. Phase Transitions in Amorphous and Crystalline Polymers / 58

2.8. Fibers / 115

2.9. Films / 123

2.10. Thermosets / 130

2.11. Differential Photocalorimetry (DPC) / 154

2.12. Fast-Scan DSC / 162

2.13. Modulated Temperature Differential Scanning Calorimetry

(MTDSC) / 168

2.14. How to Perform DSC Measurements / 208

2.15. Instrumentation / 217

Appendix / 225

Abbreviations / 225

References / 229

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